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ABSTRACT:
SUBMITTER: Kirchner MT
PROVIDER: S-EPMC2971369 | biostudies-literature | 2009 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20091007 Pt 11
In the title compound, C(6)H(3)F(3), weak electrostatic and dispersive forces between C(δ+)-F(δ-) and H(δ+)-C(δ-) groups are at the borderline of the hydrogen-bond phenomenon and are poorly directional and further deformed in the presence of π-π stacking inter-actions. The mol-ecule lies on a twofold rotation axis. In the crystal structure, one-dimensional tapes are formed via two anti-dromic C-H⋯F hydrogen bonds. These tapes are, in turn, connected into corrugated two-dimensional sheets by bifu ...[more]