Unknown

Dataset Information

0

Triaqua-bis{?-N-[N-(4-meth-oxy-2-oxidobenzyl-idene)glyc-yl]glycinato(3-)}cadmium(II)dicopper(II) dihydrate.


ABSTRACT: In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetra-dentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxyl-ate O atom. The Cd(II) atom is connected via the carboxyl-ate groups, forming a heterotrinuclear Cu(II)-Cd(II)-Cu(II) system. The Cd(II) atom is seven-coordinate in a penta-gonal-bipyramidal geometry with four O atoms from two carboxyl-ate groups and three aqua ligands. The heterotrinuclear mol-ecules are linked to the uncoordinated water mol-ecules by O-H?O hydrogen bonds into a three-dimensional framework.

SUBMITTER: Jiang J 

PROVIDER: S-EPMC2971383 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

altmetric image

Publications

Triaqua-bis{μ-N-[N-(4-meth-oxy-2-oxidobenzyl-idene)glyc-yl]glycinato(3-)}cadmium(II)dicopper(II) dihydrate.

Jiang Jiaxun J   Lu Yao Y   Yuan Limin L   Liu Wenlong W  

Acta crystallographica. Section E, Structure reports online 20091003 Pt 11


In the title compound, [CdCu(2)(C(12)H(11)N(2)O(5))(2)(H(2)O)(3)]·2H(2)O, the Cu(II) atoms are in a square plane of N(2)O(2) atoms contributed by the tetra-dentate Schiff base trianion. The Cu(II) atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxyl-ate O atom. The Cd(II) atom is connected via the carboxyl-ate groups, forming a heterotrinuclear Cu(II)-Cd(II)-Cu(II) system. The Cd(II) atom is seven-coordinate in a penta-gonal-bipyramidal geometry with  ...[more]

Similar Datasets

| S-EPMC2983767 | biostudies-literature
| S-EPMC2971010 | biostudies-literature
| S-EPMC2971438 | biostudies-literature
| S-EPMC2969992 | biostudies-literature
| S-EPMC2914968 | biostudies-literature
| S-EPMC2977345 | biostudies-literature
| S-EPMC2979099 | biostudies-literature
| S-EPMC3099980 | biostudies-literature
| S-EPMC2970494 | biostudies-literature
| S-EPMC2969951 | biostudies-literature