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Bis(hexa-methyl-enetetra-mine)bis-(tri-chloro-acetato)copper(II).

ABSTRACT: In the title compound, [Cu(C(2)Cl(3)O(2))(2)(C(6)H(12)N(4))(2)], the Cu(II) ion (site symmetry 2) is coordinated by two trichloro-acetate anions and two hexa-methyl-enetetra-mine mol-ecules, resulting in a distorted CuN(2)O(2) geometry that is inter-mediate between tetra-hedral and square planar. The Cl atoms are disordered over two sets of sites, with relative occupancies of 0.749?(7) and 0.251?(7). In the crystal, the packing is consolidated by inter-molecular C-H?O inter-actions.

SUBMITTER: Li LM

PROVIDER: S-EPMC2971390 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis(hexa-methyl-enetetra-mine)bis-(tri-chloro-acetato)copper(II).

Li Li-Min LM Jian Fang-Fang FF Li Yu-Feng YF

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

In the title compound, [Cu(C(2)Cl(3)O(2))(2)(C(6)H(12)N(4))(2)], the Cu(II) ion (site symmetry 2) is coordinated by two trichloro-acetate anions and two hexa-methyl-enetetra-mine mol-ecules, resulting in a distorted CuN(2)O(2) geometry that is inter-mediate between tetra-hedral and square planar. The Cl atoms are disordered over two sets of sites, with relative occupancies of 0.749 (7) and 0.251 (7). In the crystal, the packing is consolidated by inter-molecular C-H⋯O inter-actions. ...[more]

PMID: 21578193

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