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Chlorido(5-formyl-2-hydroxy-phenyl-?C)mercury(II).


ABSTRACT: In the planar (r.m.s. deviation = 0.027?Å) title compound, [Hg(C(7)H(5)O(2))Cl], the Hg(II) atom shows a typical linear coordination by a C atom of the benzene ring and a Cl atom. Inter-molecular O-H?O hydrogen bonds are present in the crystal structure, resulting in chains propagating along the b axis. The crystal studied was a non-merohedral twin, with a twin ratio of 0.802?(2):0.198?(2).

SUBMITTER: Zheng ZB 

PROVIDER: S-EPMC2971446 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Chlorido(5-formyl-2-hydroxy-phenyl-κC)mercury(II).

Zheng Ze-Bao ZB   Ma Shi-Ying SY   Wu Ren-Tao RT   Han Yin-Feng YF   Lu Jing-Rong JR  

Acta crystallographica. Section E, Structure reports online 20091028 Pt 11


In the planar (r.m.s. deviation = 0.027 Å) title compound, [Hg(C(7)H(5)O(2))Cl], the Hg(II) atom shows a typical linear coordination by a C atom of the benzene ring and a Cl atom. Inter-molecular O-H⋯O hydrogen bonds are present in the crystal structure, resulting in chains propagating along the b axis. The crystal studied was a non-merohedral twin, with a twin ratio of 0.802 (2):0.198 (2). ...[more]

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