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Bis[?-4,4',6,6'-tetra-chloro-2,2'-(piperazine-1,4-diyldimethyl-ene)diphenolato]dicopper(II).

ABSTRACT: In the centrosymmetric dinuclear Cu(II) title complex, [Cu(2)(C(18)H(16)Cl(4)N(2)O(2))(2)], the Cu(II) atom adopts a square-pyramidal geometry with a tetra-dentate ligand in the basal plane. The apical site is occupied by a phenolate O atom from an adjacent ligand, forming a dimer. The mol-ecular structure is stabilized by intra-molecular C-H?O and C-H?Cl hydrogen bonds.

SUBMITTER: Kubono K

PROVIDER: S-EPMC2971750 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Bis[μ-4,4',6,6'-tetra-chloro-2,2'-(piperazine-1,4-diyldimethyl-ene)diphenolato]dicopper(II).

Kubono Koji K Noshita Chisato C Tani Keita K Yokoi Kunihiko K

Acta crystallographica. Section E, Structure reports online 20091128 Pt 12

In the centrosymmetric dinuclear Cu(II) title complex, [Cu(2)(C(18)H(16)Cl(4)N(2)O(2))(2)], the Cu(II) atom adopts a square-pyramidal geometry with a tetra-dentate ligand in the basal plane. The apical site is occupied by a phenolate O atom from an adjacent ligand, forming a dimer. The mol-ecular structure is stabilized by intra-molecular C-H⋯O and C-H⋯Cl hydrogen bonds. ...[more]

PMID: 21578691

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