Methyl 4,5-diacet-oxy-1-oxo-2-phenyl-perhydro-4,6-epoxy-cyclo-penta-[c]pyridine-7-carboxyl-ate ethanol solvate.
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ABSTRACT: The title compound, the product of an acid-catalysed Wagner-Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C(20)H(21)NO(8)·C(2)H(6)O. The title mol-ecule comprises a fused tricyclic system containing two five-membered rings (cyclo-pentane and tetra-hydro-furan) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist-boat conformation.
SUBMITTER: Gurbanov AV
PROVIDER: S-EPMC2971959 | biostudies-literature |
REPOSITORIES: biostudies-literature
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