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6-Chloro-N,N-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl-formamide monosolvate.

ABSTRACT: The title compound, C(17)H(16)ClN(5)·C(3)H(7)NO, was prepared by reaction of p-toluidine with 2,4,6-trichloro-1,3,5-triazine at room temperature. The dihedral angles between the triazine ring and the pendant rings are 3.61?(12) and 53.11?(12)°. An intra-molecular C-H?N inter-action occurs. The packing is stabilized by N-H?N and N-H?O hydrogen bonds and C-H?? and ?-? [centroid-centroid distance = 3.763?(1)?Å] inter-actions.

SUBMITTER: Jian F

PROVIDER: S-EPMC2972005 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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6-Chloro-N,N-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl-formamide monosolvate.

Jian Fangfang F Xiao Hailian H Wei Yongxiang Y

Acta crystallographica. Section E, Structure reports online 20091125 Pt 12

The title compound, C(17)H(16)ClN(5)·C(3)H(7)NO, was prepared by reaction of p-toluidine with 2,4,6-trichloro-1,3,5-triazine at room temperature. The dihedral angles between the triazine ring and the pendant rings are 3.61 (12) and 53.11 (12)°. An intra-molecular C-H⋯N inter-action occurs. The packing is stabilized by N-H⋯N and N-H⋯O hydrogen bonds and C-H⋯π and π-π [centroid-centroid distance = 3.763 (1) Å] inter-actions. ...[more]

PMID: 21578920

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