Ontology highlight
ABSTRACT:
SUBMITTER: Li J
PROVIDER: S-EPMC2972053 | biostudies-literature | 2009 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20091107 Pt 12
The title complex, [Fe(2)(C(2)H(5)S)(3)(C(12)H(21)Si)(2)], has an unusual Fe(2)S(3) core. The two 1,2,3,4-tetra-methyl-5-(trimethyl-silyl)cyclo-penta-dienyl (Cp') ligands coordinate to the Fe atoms with their C(5) planes perpendicular [dihedral angles = 88.23 (7) and 88.55 (7)°] to the Fe-Fe vector, building two Cp'Fe subunits. These two subunits are bridged by three thiol-ate ligands. There are no significant differences in the coordination geometries between the two Fe atoms. The short Fe-Fe d ...[more]