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(Acetyl-acetonato-?O,O')aqua-[2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-?O)acetohydrazidato-?O,N']manganese(III).

ABSTRACT: In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a phen-oxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-?O)acetohydrazidate dianion, by two O atoms of the acetyl-acetonate anion and by the O atom of a coordinated water mol-ecule. In the crystal structure, complex mol-ecules are linked into centrosymmetric dimeric units through four inter-molecular O-H?O hydrogen bonds involving both H atoms of the coordinated water mol-ecule.

SUBMITTER: Xiao ZJ

PROVIDER: S-EPMC2977142 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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(Acetyl-acetonato-κO,O')aqua-[2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidato-κO,N']manganese(III).

Xiao Zi-Jing ZJ

Acta crystallographica. Section E, Structure reports online 20090725 Pt 8

In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a phen-oxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidate dianion, by two O atoms of the acetyl-acetonate anion and by the O atom of a coordinated water mol-ecule. In the crystal structure, complex mol-ecules are linked into centrosymmetric dimeric units through four i ...[more]

PMID: 21583428

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