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2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol.

ABSTRACT: The title mol-ecule, C(7)H(15)NO(5), the major product from selective enzymatic oxidation followed by hydrogeno-lysis of the corresponding azido-heptitol, was found by X-ray crystallography to exisit in a chair conformation with three axial hydroxyl groups. One of the hydroxymethyl groups is disordered over two sets of sites in a 0.590?(3):0.410?(3) ratio. In the crystal, O-H?O, O-H?(O,O), O-H?N and N-H?O hydrogen bonding occurs.

SUBMITTER: Jenkinson SF

PROVIDER: S-EPMC2977159 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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2,6-Dide-oxy-2,6-imino-l-glycero-d-ido-heptitol.

Jenkinson Sarah F SF Booth K Victoria KV Newberry Scott S Fleet George W J GW Izumori Ken K Morimoto Kenji K Nash Robert J RJ Jones Laurence L Watkin David J DJ Thompson Amber L AL

Acta crystallographica. Section E, Structure reports online 20090704 Pt 8

The title mol-ecule, C(7)H(15)NO(5), the major product from selective enzymatic oxidation followed by hydrogeno-lysis of the corresponding azido-heptitol, was found by X-ray crystallography to exisit in a chair conformation with three axial hydroxyl groups. One of the hydroxymethyl groups is disordered over two sets of sites in a 0.590 (3):0.410 (3) ratio. In the crystal, O-H⋯O, O-H⋯(O,O), O-H⋯N and N-H⋯O hydrogen bonding occurs. ...[more]

PMID: 21583466

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