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Tetra-aqua-bis(3,5-di-4-pyridyl-1,2,4-triazolato-?N)nickel(II) dihydrate.

ABSTRACT: The Ni(II) atom in the title compound, [Ni(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, lies on a center of inversion and is coordinated by the N atoms of two 3,5-di-4-pyridine-1,2,4-triazolate ligands and by four water O atoms in a slightly distorted octa-hedral geometry. The coordinated and uncoordinated water mol-ecules inter-act with the N-heterocycles through O-H?N and O-H?O hydrogen bonds, generating a three-dimensional supra-molecular architecture.

SUBMITTER: Dong LY 

PROVIDER: S-EPMC2977209 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis(3,5-di-4-pyridyl-1,2,4-triazolato-κN)nickel(II) dihydrate.

Dong Lin Yi LY  

Acta crystallographica. Section E, Structure reports online 20090722 Pt 8

The Ni(II) atom in the title compound, [Ni(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, lies on a center of inversion and is coordinated by the N atoms of two 3,5-di-4-pyridine-1,2,4-triazolate ligands and by four water O atoms in a slightly distorted octa-hedral geometry. The coordinated and uncoordinated water mol-ecules inter-act with the N-heterocycles through O-H⋯N and O-H⋯O hydrogen bonds, generating a three-dimensional supra-molecular architecture. ...[more]

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