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Hemiaqua-bis(2-fluoro-benzoato-?O,O')bis-(1,10-phenanthroline-?N,N')lead(II) dihydrate.

ABSTRACT: In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluoro-benzoate ligands and a half-occupied water mol-ecule in an irregular coordination geometry. One carboxyl-ate O atom and two F atoms are each disordered over two sites with occupancy factors of 0.558?(6) and 0.442?(6). The two crystallographically independent phen ligands are co-planar [dihedral angle 0.0?(2)°]. Centroid-centroid distances of 3.659?(7) and 3.687?(7)?Å indicate ?-? stacking inter-actions between neighboring phen ligands. In the crystal, O-H?O, C-H?F and C-H?O hydrogen bonds link the complex mol-ecules and uncoordinated water mol-ecules into a supra-molecular network.

SUBMITTER: Ye SF

PROVIDER: S-EPMC2977250 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Hemiaqua-bis(2-fluoro-benzoato-κO,O')bis-(1,10-phenanthroline-κN,N')lead(II) dihydrate.

Ye Su-Fang SF Zhang Bi-Song BS

Acta crystallographica. Section E, Structure reports online 20090718 Pt 8

In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluoro-benzoate ligands and a half-occupied water mol-ecule in an irregular coordination geometry. One carboxyl-ate O atom and two F atoms are each disordered over two sites with occupancy factors of 0.558 (6) and 0.442 (6). The two crystallographically independent phen ligands a ...[more]

PMID: 21583389

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Bis(2-fluoro-benzoato-?O,O')bis-(1,10-phenanthroline-?N,N')lead(II) dihydrate.

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