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N'-(3-Methoxy-benzyl-idene)aceto-hydrazide.


ABSTRACT: In the title mol-ecule, C(10)H(12)N(2)O(2), the acetohydrazide group is planar within 0.012?(1)?Å and forms a dihedral angle of 5.25?(8)° with the benzene ring. The meth-oxy group is coplanar with the attached benzene ring [C-O-C-C = 0.1?(2)°]. The mol-ecule adopts a trans configuration with respect to the C=N double bond. In the crystal, mol-ecules are linked into centrosymmetric dimers by N-H?O hydrogen bonds and these dimers are linked into a ribbon-like structure along [110] by C-H?O hydrogen bonds. In addition, an inter-molecular C-H?? inter-action is observed.

SUBMITTER: Lv LP 

PROVIDER: S-EPMC2977277 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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N'-(3-Methoxy-benzyl-idene)aceto-hydrazide.

Lv Lu-Ping LP   Yu Tie-Ming TM   Yu Wen-Bo WB   Li Wei-Wei WW   Hu Xian-Chao XC  

Acta crystallographica. Section E, Structure reports online 20090725 Pt 8


In the title mol-ecule, C(10)H(12)N(2)O(2), the acetohydrazide group is planar within 0.012 (1) Å and forms a dihedral angle of 5.25 (8)° with the benzene ring. The meth-oxy group is coplanar with the attached benzene ring [C-O-C-C = 0.1 (2)°]. The mol-ecule adopts a trans configuration with respect to the C=N double bond. In the crystal, mol-ecules are linked into centrosymmetric dimers by N-H⋯O hydrogen bonds and these dimers are linked into a ribbon-like structure along [110] by C-H⋯O hydroge  ...[more]

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