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Dichloridobis{6-methyl-2-[(trimethyl-silyl)amino]pyridine-?N}cobalt(II).

ABSTRACT: In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra-hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl-silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06?(5)°. Cohesion within the crystal structure is accomplished by N-H?Cl hydrogen bonds.

SUBMITTER: Xue X

PROVIDER: S-EPMC2977306 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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Dichloridobis{6-methyl-2-[(trimethyl-silyl)amino]pyridine-κN}cobalt(II).

Xue Xiaoyan X Chen Xia X Tong Hongbo H

Acta crystallographica. Section E, Structure reports online 20090722 Pt 8

In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra-hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl-silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N-H⋯Cl hydrogen bonds. ...[more]

PMID: 21583404

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