Unknown

Dataset Information

0

Dichloridobis{6-methyl-2-[(trimethyl-silyl)amino]pyridine-?N}cobalt(II).


ABSTRACT: In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra-hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl-silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06?(5)°. Cohesion within the crystal structure is accomplished by N-H?Cl hydrogen bonds.

SUBMITTER: Xue X 

PROVIDER: S-EPMC2977306 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

altmetric image

Publications

Dichloridobis{6-methyl-2-[(trimethyl-silyl)amino]pyridine-κN}cobalt(II).

Xue Xiaoyan X   Chen Xia X   Tong Hongbo H  

Acta crystallographica. Section E, Structure reports online 20090722 Pt 8


In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra-hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl-silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N-H⋯Cl hydrogen bonds. ...[more]

Similar Datasets

| S-EPMC2983604 | biostudies-literature
| S-EPMC3007936 | biostudies-literature
| S-EPMC2983314 | biostudies-literature
| S-EPMC2960254 | biostudies-literature
| S-EPMC3470146 | biostudies-literature
| S-EPMC3200706 | biostudies-literature
| S-EPMC3201495 | biostudies-literature
| S-EPMC2969585 | biostudies-literature
| S-EPMC3884428 | biostudies-literature
| S-EPMC3151933 | biostudies-literature