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Aqua-chloridobis[5-(2-pyrid-yl)-1H-tetra-zolato-?N]iron(III).

ABSTRACT: The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydro-thermal reaction of FeCl(3) with 2-(1H-tetra-zol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octa-hedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom and one chloride anion. The pyridine and tetra-zole rings are nearly coplanar [dihedral angles = 4.32?(15) and 5.04?(14)°]. In the crystal structure, inter-molecular O-H?N hydrogen bonds link the complex mol-ecules into a two-dimensional network parallel to (100).

SUBMITTER: Wang B 

PROVIDER: S-EPMC2977327 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Aqua-chloridobis[5-(2-pyrid-yl)-1H-tetra-zolato-κN]iron(III).

Wang Bo B  

Acta crystallographica. Section E, Structure reports online 20090701 Pt 8

The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydro-thermal reaction of FeCl(3) with 2-(1H-tetra-zol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octa-hedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom and one chloride anion. The pyridine and tetra-zole rings are nearly coplanar [dihedral angles = 4.32 (15) and 5.04 (14)°]. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds link the com  ...[more]

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