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5-Fluoro-3-methyl-sulfinyl-2-phenyl-1-benzofuran.

ABSTRACT: In the title compound, C(15)H(11)FO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The 2-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 32.1?(2)°. The crystal structure is stabilized by aromatic ?-? inter-actions between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.690?(5)?Å]. In addition, the crystal structure exhibits inter-molecular C-H?O and C-H?F inter-actions.

SUBMITTER: Choi HD

PROVIDER: S-EPMC2977333 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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5-Fluoro-3-methyl-sulfinyl-2-phenyl-1-benzofuran.

Choi Hong Dae HD Seo Pil Ja PJ Son Byeng Wha BW Lee Uk U

Acta crystallographica. Section E, Structure reports online 20090722 Pt 8

In the title compound, C(15)H(11)FO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The 2-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 32.1 (2)°. The crystal structure is stabilized by aromatic π-π inter-actions between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.690 (5) Å]. In addition, the crystal structure exhibits inter-molecular C-H⋯O and ...[more]

PMID: 21583635

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