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2-Bromo-N-(2-chloro-phen-yl)acetamide.

ABSTRACT: The conformation of the N-H bond in the structure of the title compound, C(8)H(7)BrClNO, is syn to the 2-chloro substituent in the aniline ring and anti to both the C=O and C-Br bonds in the side chain, similar to that observed in 2-chloro-N-(2-chloro-phen-yl)acetamide. In the crystal, mol-ecules are linked into chains along the a axis by N-H?O hydrogen bonds. These chains are in turn linked into pairs, in the form of columns, through much weaker C-H?Cl and Br?Br [4.3027?(3)?Å] inter-actions.

SUBMITTER: Gowda BT 

PROVIDER: S-EPMC2977351 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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2-Bromo-N-(2-chloro-phen-yl)acetamide.

Gowda B Thimme BT   Foro Sabine S   Suchetan P A PA   Fuess Hartmut H   Terao Hiromitsu H  

Acta crystallographica. Section E, Structure reports online 20090725 Pt 8

The conformation of the N-H bond in the structure of the title compound, C(8)H(7)BrClNO, is syn to the 2-chloro substituent in the aniline ring and anti to both the C=O and C-Br bonds in the side chain, similar to that observed in 2-chloro-N-(2-chloro-phen-yl)acetamide. In the crystal, mol-ecules are linked into chains along the a axis by N-H⋯O hydrogen bonds. These chains are in turn linked into pairs, in the form of columns, through much weaker C-H⋯Cl and Br⋯Br [4.3027 (3) Å] inter-actions. ...[more]

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