Unknown

Dataset Information

0

Triaqua-dichlorido[5-(4-pyridinio)tetra-zolato-?N]cobalt(II) monohydrate.

ABSTRACT: The title compound, [CoCl(2)(C(6)H(5)N(5))(H(2)O)(3)]·H(2)O, was synthesized by hydro-thermal reaction of CoCl(2) with 4-(2H-tetra-zol-5-yl)pyridine. The Co(II) cation is coordinated by two Cl(-) ions, one N atom from the 5-(4-pyridinio)tetra-zolate zwitterion and three O atoms from three water mol-ecules in a distorted octa-hedral geometry. In the crystal, mol-ecules are linked into a three-dimensional network by N-H?Cl hydrogen bonds and O-H?O/N/Cl hydrogen bonds involv-ing both coordinated and uncoordinated water mol-ecules. Strong ?-? stacking is present between parallel pyridinium and tetra-zolate rings [centroid-centroid distances = 3.411?(2) and 3.436?(2)?Å].

SUBMITTER: Wang B 

PROVIDER: S-EPMC2977361 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Triaqua-dichlorido[5-(4-pyridinio)tetra-zolato-κN]cobalt(II) monohydrate.

Wang Bo B  

Acta crystallographica. Section E, Structure reports online 20090701 Pt 8

The title compound, [CoCl(2)(C(6)H(5)N(5))(H(2)O)(3)]·H(2)O, was synthesized by hydro-thermal reaction of CoCl(2) with 4-(2H-tetra-zol-5-yl)pyridine. The Co(II) cation is coordinated by two Cl(-) ions, one N atom from the 5-(4-pyridinio)tetra-zolate zwitterion and three O atoms from three water mol-ecules in a distorted octa-hedral geometry. In the crystal, mol-ecules are linked into a three-dimensional network by N-H⋯Cl hydrogen bonds and O-H⋯O/N/Cl hydrogen bonds involv-ing both coordinated an  ...[more]

Similar Datasets

Unknown Diaqua-dichlorido[5-(3-pyridinio)tetra-zolato-?N]copper(II) dihydrate.
| S-EPMC2970193 | biostudies-other
Unknown Bis[?-5-(2-pyrid-yl)tetra-zolato]-?N,N:N;?N:N,N-bis-[triaqua-zinc(II)] bis-(trifluoro-acetate) monohydrate.
| S-EPMC2977136 | biostudies-literature
Unknown Triaqua-chlorido(1,10-phenanthroline-?N,N')cobalt(II) chloride monohydrate.
| S-EPMC2968016 | biostudies-literature
Unknown Tetra-kis(4-amino-pyridine-?N)dichlorido-copper(II) monohydrate.
| S-EPMC2961768 | biostudies-literature
Unknown Bis[?-5-(5-carboxyl-ato-3-pyrid-yl)tetra-zolato-?N,N:N]bis-[triaqua-zinc(II)].
| S-EPMC2969057 | biostudies-literature
Unknown Crystal structure of cis-tetra-aqua-dichlorido-cobalt(II) sulfolane disolvate.
| S-EPMC4384590 | biostudies-literature
Unknown Triaqua-(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-?O,O,O)cobalt(II) monohydrate.
| S-EPMC3212185 | biostudies-literature
Unknown Triaqua-(3-carb-oxy-5-sulfonatobenzoato-κO)(1,10-phenanthroline-κN,N')cobalt(II) monohydrate.
| S-EPMC2961914 | biostudies-literature
Unknown Tetra-kis(2-amino-pyrazine-?N)dichlorido-cobalt(II).
| S-EPMC2972178 | biostudies-other
Unknown Dichlorido[bis-(2-ethyl-5-methyl-1H-imidazol-4-yl-?N)methane]-cobalt(II) monohydrate.
| S-EPMC3089236 | biostudies-literature