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A new coordination tetra-mer of copper(I) iodide and benzyl-dimethyl-amine: tetra-?(3)-iodido-tetra-kis[(benzyl-dimethyl-amine-?N)copper(I)].

ABSTRACT: The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand. Each I atom acts as a ?(3)-ligand, linking three Cu(I) atoms. The Cu-I bond distances vary between 2.6328?(7) and 2.7121?(6)?Å, while the Cu-N bond distances vary between 2.107?(3) and 2.122?(3)?Å.

SUBMITTER: Yang S

PROVIDER: S-EPMC2977424 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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A new coordination tetra-mer of copper(I) iodide and benzyl-dimethyl-amine: tetra-μ(3)-iodido-tetra-kis[(benzyl-dimethyl-amine-κN)copper(I)].

Yang Shuying S Li Yuebao Y Cui Yujie Y Pan Jianguo J

Acta crystallographica. Section E, Structure reports online 20090711 Pt 8

The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu-I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu-N bond distances vary between 2.107 (3) and 2.122 (3) Å. ...[more]

PMID: 21583366

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