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Di-?-perchlorato-bis-{?-2-[(2-pyrid-yl)methyl-amino-meth-yl]phenolato)dicopper(II) acetonitrile disolvate.

ABSTRACT: In the crystal of the dinuclear title compound, [Cu(2)(C(13)H(13)N(2)O)(2)(ClO(4))(2)]·2CH(3)CN, the two bridging perchlorate ions chelate to the two Cu(II) atoms in a ?-O:O' fashion on opposite sides of the equatorial plane. The Cu(II) ions display a distorted octa-hedral coordination geometry (in the usual 4 + 2 Jahn-Teller arrangement), each being coordinated by two O atoms from the two perchlorate ligands, and two N and O atoms from the reduced Schiff base ligand. The asymmetric unit contains two acetonitrile solvent mol-ecules. In the crystal structure, in addition to N-H?O hydrogen bonds, there are weak C-H?O inter-actions between the perchlorate O atoms and the reduced Schiff base ligand. C-H?N inter-actions are also present.

SUBMITTER: Assey GE

PROVIDER: S-EPMC2977449 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Di-μ-perchlorato-bis-{μ-2-[(2-pyrid-yl)methyl-amino-meth-yl]phenolato)dicopper(II) acetonitrile disolvate.

Assey Gervas E GE Yisgedu Teshome T Gultneh Yilma Y Butcher Ray J RJ Tesema Yohannes Y

Acta crystallographica. Section E, Structure reports online 20090729 Pt 8

In the crystal of the dinuclear title compound, [Cu(2)(C(13)H(13)N(2)O)(2)(ClO(4))(2)]·2CH(3)CN, the two bridging perchlorate ions chelate to the two Cu(II) atoms in a μ-O:O' fashion on opposite sides of the equatorial plane. The Cu(II) ions display a distorted octa-hedral coordination geometry (in the usual 4 + 2 Jahn-Teller arrangement), each being coordinated by two O atoms from the two perchlorate ligands, and two N and O atoms from the reduced Schiff base ligand. The asymmetric unit contain ...[more]

PMID: 21583306

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