Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

9-Benzyl-3-bromo-9H-carbazole.

ABSTRACT: The title compound, C(19)H(14)BrN, was synthesized by the N-alkyl-ation of (chloro-meth-yl)benzene with 3-bromo-9H-carbazole. The carbazole ring system is essentially planar (r.m.s. deviation = 0.013?Å) and forms a dihedral angle of 87.1?(2)° with the phenyl ring.

SUBMITTER: Huang PM

PROVIDER: S-EPMC2977497 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

9-Benzyl-3-bromo-9H-carbazole.

Huang Peng-Mian PM Wang Xiao-Chun XC

Acta crystallographica. Section E, Structure reports online 20090704 Pt 8

The title compound, C(19)H(14)BrN, was synthesized by the N-alkyl-ation of (chloro-meth-yl)benzene with 3-bromo-9H-carbazole. The carbazole ring system is essentially planar (r.m.s. deviation = 0.013 Å) and forms a dihedral angle of 87.1 (2)° with the phenyl ring. ...[more]

PMID: 21583473

Similar Datasets

9-Benzyl-9H-carbazole.

Project description:The asymmetric unit of the title compound, C(19)H(15)N, contains two crystallographically independent mol-ecules. In both mol-ecules, the planar carbazole moieties [maximum deviations = 0.037?(4) and 0.042?(3)?Å] are oriented with respect to the adjacent benzene rings, at dihedral angles of 85.29?(8) and 89.89?(7)°, respectively. In the crystal structure, weak C-H?? inter-actions are observed involving the carbazole rings.

| S-EPMC2979278 | biostudies-literature

9-(2-Bromo-eth-yl)-9H-carbazole.

Project description:In the title compound, C(14)H(12)BrN, the fused-ring system is slightly buckled as its two benzene rings are inclined to one another by 3.41?(14)°.

| S-EPMC3393295 | biostudies-literature

9-(4-Bromo-but-yl)-9H-carbazole.

Project description:In the title compound, C(16)H(16)BrN, the tricyclic carbazole system is essentially planar (r.m.s. deviation of all non-H atoms = 0.010?Å). The dihedral angle between the two outer carbazole rings is 1.1?(3)°. There are no directional inter-molecular contacts in the crystal packing.

| S-EPMC3379420 | biostudies-literature

9-(4-Bromo-but-yl)-9H-carbazole.

Project description:In the title compound, C(16)H(16)BrN, the bromo-butyl group lies on one side of the carbazole ring plane and has a zigzag shape. The dihedral angle between the two benzene rings is 0.55°. In the crystal, mol-ecules are connected by van der Waals inter-actions.

| S-EPMC3344060 | biostudies-literature

9-(4-Bromo-phen-yl)-9H-carbazole.

Project description:In the title mol-ecule, C18H12BrN, the 4-bromo-phenyl ring is inclined to the mean plane of the carbazole moiety (r.m.s. devation = 0.027 Å) by 49.87 (5)°. In the crystal, molecules stack along [001] and are linked by C-H⋯π interactions forming a corrugated two-dimensional network lying parallel to (100).

| S-EPMC3998433 | biostudies-literature

2,3,6,7-Tetra-bromo-9-butyl-9H-carbazole.

Project description:In he title compound, C(16)H(13)Br(4)N, the carbazole skeleton is nearly planar [maximum deviation = 0.026 (4) Å] and makes a dihedral angle of 73.8 (4)° with the butyl chain. The butyl chain adopts a trans conformation. In the crystal, mol-ecules are linked by π-π stacking inter-actions [centroid-centroid distance = 3.559 (2) Å].

| S-EPMC3344475 | biostudies-literature

3,6-Dibromo-9-(4-bromo-benz-yl)-9H-carbazole.

Project description:The title compound, C(19)H(12)Br(3)N, was synthesized by N-alkyl-ation of 1-bromo-4-(bromo-meth-yl)benzene with 3,6-dibromo-9H-carbazole. There are two unique mol-ecules in the asymmetric unit. The carbazole ring system is essentially planar, with a mean deviation of 0.0402?Å for one mol-ecule and 0.0279?Å for the other. The carbazole planes are inclined to the benzene ring planes at dihedral angles of 58.3?(3) and 71.1?(3)° in the two mol-ecules.

| S-EPMC2968375 | biostudies-literature

3-Bromo-9-(4-fluoro-benz-yl)-9H-carbazole.

Project description:The title compound, C(19)H(13)BrFN, was synthesized by N-alkyl-ation of 1-chloro-methyl-4-fluoro-benzene with 3-bromo-9H-carbazole. The carbazole ring system is essentially planar (r.m.s. deviation of 0.024?Å for the non-H atoms) and forms a dihedral angle of 88.2?(3)° with the benzene ring.

| S-EPMC2969443 | biostudies-literature

Crystal structure of 3-bromo-9-ethyl-9H-carbazole.

Project description:In the title compound, C14H12BrN, the tricyclic ring system is essentially planar (r.m.s. deviation 0.026 Å). The carbon atoms of the ethyl group deviate from the mean plane by 0.148 (9) (CH2) and 1.59 (1) Å (CH3). In the crystal, H⋯π contacts [2.698-2.898 Å] shorter than the van der Waals contact distance of 3.70 Å are observed. A scalable to gram quantities selective synthesis of mono-bromine-substituted carbazole derivatives was developed.

| S-EPMC4719982 | biostudies-literature

Crystal structure of 1,3,6,8-tetra-bromo-9-ethyl-9H-carbazole.

Project description:In the title compound, C14H9Br4N, the tricyclic ring system is almost planar (r.m.s. deviation for the 13 non-H atoms = 0.017 Å) and the methyl C atom deviates from the mean plane of the ring system by 1.072 (17) Å. In the crystal, Br⋯Br contacts [3.636 (3) and 3.660 (3) Å] slightly shorter than the van der Waals contact distance of 3.70 Å are seen.

| S-EPMC4459356 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data