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Piperazinediium tetra-chloridozincate(II).

ABSTRACT: In the title compound, (C(4)H(12)N(2))[ZnCl(4)], the Zn atom adopts a slightly distorted tetra-hedral geometry. In the crystal, the dication and dianion inter-act by way of N-H?Cl and N-H?(Cl,Cl) hydrogen bonds to result in a layered network propagating in (010). The hydrogen-bonding network is unbalanced, with three Cl atoms accepting two hydrogen bonds each and one Cl atom not accepting any hydrogen bonds: the latter shows the shortest Zn-Cl bond length. The crystal studied was found to be an inversion twin.

SUBMITTER: Sutherland PA 

PROVIDER: S-EPMC2977610 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Piperazinediium tetra-chloridozincate(II).

Sutherland Pamela A PA   Harrison William T A WT  

Acta crystallographica. Section E, Structure reports online 20090425 Pt 5

In the title compound, (C(4)H(12)N(2))[ZnCl(4)], the Zn atom adopts a slightly distorted tetra-hedral geometry. In the crystal, the dication and dianion inter-act by way of N-H⋯Cl and N-H⋯(Cl,Cl) hydrogen bonds to result in a layered network propagating in (010). The hydrogen-bonding network is unbalanced, with three Cl atoms accepting two hydrogen bonds each and one Cl atom not accepting any hydrogen bonds: the latter shows the shortest Zn-Cl bond length. The crystal studied was found to be an  ...[more]

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