Unknown

Dataset Information

0

Piperazinediium tetra-chloridozincate(II).

ABSTRACT: In the title compound, (C(4)H(12)N(2))[ZnCl(4)], the Zn atom adopts a slightly distorted tetra-hedral geometry. In the crystal, the dication and dianion inter-act by way of N-H?Cl and N-H?(Cl,Cl) hydrogen bonds to result in a layered network propagating in (010). The hydrogen-bonding network is unbalanced, with three Cl atoms accepting two hydrogen bonds each and one Cl atom not accepting any hydrogen bonds: the latter shows the shortest Zn-Cl bond length. The crystal studied was found to be an inversion twin.

SUBMITTER: Sutherland PA 

PROVIDER: S-EPMC2977610 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Piperazinediium tetra-chloridozincate(II).

Sutherland Pamela A PA   Harrison William T A WT  

Acta crystallographica. Section E, Structure reports online 20090425 Pt 5

In the title compound, (C(4)H(12)N(2))[ZnCl(4)], the Zn atom adopts a slightly distorted tetra-hedral geometry. In the crystal, the dication and dianion inter-act by way of N-H⋯Cl and N-H⋯(Cl,Cl) hydrogen bonds to result in a layered network propagating in (010). The hydrogen-bonding network is unbalanced, with three Cl atoms accepting two hydrogen bonds each and one Cl atom not accepting any hydrogen bonds: the latter shows the shortest Zn-Cl bond length. The crystal studied was found to be an  ...[more]

Similar Datasets

Unknown Bis(2-aminopyridinium) tetra-chloridozincate(II).
| S-EPMC3011649 | biostudies-literature
Unknown (2R)-2-Methyl-piperazinediium tetra-chloridocuprate(II).
| S-EPMC2984032 | biostudies-literature
Unknown Bis(S-benzyl-isothio-uronium) tetra-chloridozincate(II).
| S-EPMC2961438 | biostudies-literature
Unknown (S)-1,2,4-Trimethyl-piperazine-1,4-diium tetra-chloridozincate(II).
| S-EPMC3007566 | biostudies-literature
Unknown 2,2'-(Butane-1,4-di-yl)diisoquinolinium tetra-chloridozincate(II).
| S-EPMC2959863 | biostudies-literature
Unknown 2,2'-(Hexane-1,6-di-yl)diisoquinolinium tetra-chloridozincate(II).
| S-EPMC2969707 | biostudies-literature
Unknown 2-Methyl-piperazinediium tetra-chlorido-zincate(II).
| S-EPMC2979142 | biostudies-other
Unknown Piperazinediium tetra-chloridocadmate monohydrate.
| S-EPMC3051944 | biostudies-literature
Unknown Bis(2-amino-1,3-benzothia-zol-3-ium) tetra-chloridozincate(II).
| S-EPMC3120423 | biostudies-literature
Unknown 4-(3-Ammonio-prop-yl)morpholin-4-ium tetra-chloridozincate(II).
| S-EPMC2968592 | biostudies-literature