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[1,2-Bis(diphenyl-phosphino)-1,2-dicarba-closo-dodeca-borane-?P,P'][7,8-bis-(di-phenyl-phosphino)-7,8-dicarba-nido-undeca-borato-?P,P']gold(I)-dichloro-methane-water (2/1/1).

ABSTRACT: The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol-ecules in the asymmetric unit. The gold(I) centres display a distorted tetra-hedral geometry. The complex is stablized through weak intra-molecular ?-? stacking (Cg?Cg = 4.17?Å) and edge-to-face inter-actions (H?Cg = 3.21?Å). Adjacent mol-ecules inter-act through C-H?? (H?Cg = 2.88?Å) and B-H?? (H?Cg = 3.15?Å) contacts, forming a three-dimensional network, with solvent mol-ecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35.

SUBMITTER: Ioppolo JA 

PROVIDER: S-EPMC2977637 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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[1,2-Bis(diphenyl-phosphino)-1,2-dicarba-closo-dodeca-borane-κP,P'][7,8-bis-(di-phenyl-phosphino)-7,8-dicarba-nido-undeca-borato-κP,P']gold(I)-dichloro-methane-water (2/1/1).

Ioppolo Joseph A JA   Clegg Jack K JK   Rendina Louis M LM  

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5

The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol-ecules in the asymmetric unit. The gold(I) centres display a distorted tetra-hedral geometry. The complex is stablized through weak intra-molecular π-π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face inter-actions (H⋯Cg = 3.21 Å). Adjacent mol-ecules inter-act through C-H⋯π (H⋯Cg = 2.88 Å) and B-H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent m  ...[more]

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