Unknown

Dataset Information

0

[1,2-Bis(diphenyl-phosphino)-1,2-dicarba-closo-dodeca-borane-?P,P'][7,8-bis-(di-phenyl-phosphino)-7,8-dicarba-nido-undeca-borato-?P,P']gold(I)-dichloro-methane-water (2/1/1).

ABSTRACT: The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol-ecules in the asymmetric unit. The gold(I) centres display a distorted tetra-hedral geometry. The complex is stablized through weak intra-molecular ?-? stacking (Cg?Cg = 4.17?Å) and edge-to-face inter-actions (H?Cg = 3.21?Å). Adjacent mol-ecules inter-act through C-H?? (H?Cg = 2.88?Å) and B-H?? (H?Cg = 3.15?Å) contacts, forming a three-dimensional network, with solvent mol-ecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35.

SUBMITTER: Ioppolo JA 

PROVIDER: S-EPMC2977637 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

[1,2-Bis(diphenyl-phosphino)-1,2-dicarba-closo-dodeca-borane-κP,P'][7,8-bis-(di-phenyl-phosphino)-7,8-dicarba-nido-undeca-borato-κP,P']gold(I)-dichloro-methane-water (2/1/1).

Ioppolo Joseph A JA   Clegg Jack K JK   Rendina Louis M LM  

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5

The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol-ecules in the asymmetric unit. The gold(I) centres display a distorted tetra-hedral geometry. The complex is stablized through weak intra-molecular π-π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face inter-actions (H⋯Cg = 3.21 Å). Adjacent mol-ecules inter-act through C-H⋯π (H⋯Cg = 2.88 Å) and B-H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent m  ...[more]

Similar Datasets

Unknown [1,2-Bis(diisopropyl-phosphino)-1,2-dicarba-closo-dodeca-borane-?P,P']dichloridomercury(II).
| S-EPMC2915082 | biostudies-other
Unknown Di-?-thio-cyanato-bis-{[1,2-bis-(diiso-propyl-phosphan-yl)-1,2-dicarba-closo-dodeca-borane]silver(I)}.
| S-EPMC3050408 | biostudies-literature
Unknown (1,2-Dicarba-closo-dodeca-boran-yl)trimethyl-methanaminium iodide.
| S-EPMC3213586 | biostudies-literature
Unknown Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].
| S-EPMC4257441 | biostudies-other
Unknown Crystal structure of 1-butyl-2,3-di-methyl-imidazolium dicarba-7,8-nido-undeca-borate.
| S-EPMC4350724 | biostudies-literature
Unknown Crystal structure of 1,1'-bis[1,7-dicarba-closo-dodeca-borane(11)].
| S-EPMC4257294 | biostudies-literature
Unknown Bis(8-methyl-2,8-dicarba-closo-dodeca-boran-2-yl) tris-elenide.
| S-EPMC3212301 | biostudies-literature
Unknown Bis(?-nitrato-?(2) O:O)bis-{[1,2-bis-(diiso-propyl-phosphan-yl)-1,2-dicarba-closo-dodeca-borane-?(2) P,P']silver(I)} di-chloro-methane disolvate.
| S-EPMC3998584 | biostudies-literature
Unknown 9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca-borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9)).
| S-EPMC3006814 | biostudies-other
Unknown [1,2-Bis(di-cyclo-hexyl-phosphan-yl)-1,2-dicarba-closo-dodeca-borane-2?(2) P,P']di-?-chlorido-1:2?(4) Cl:Cl-di-chlorido-1?(2) Cl-dimercury(II).
| S-EPMC3998597 | biostudies-literature