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2-(Benzo[d]thia-zol-2-ylsulfan-yl)-N-(6-methyl-2-pyrid-yl)acetamide.

ABSTRACT: In the title compound, C(15)H(13)N(3)OS(2), the pyridine ring and the benzo[d]thia-zole unit subtend a dihedral angle of 57.7?(2)°. The length of the C(sp) (2)-S bond [1.7462?(17)?Å] is significantly shorter than that of the C(sp) (3)-S bond [1.8133?(18)?Å]. The crystal structure is stabilized by intra-molecular N-H?N and inter-molecular C-H?O and C-H?N hydrogen-bond inter-actions. Furthermore, C-H?? inter-actions stabilize the crystal packing.

SUBMITTER: Zhao B

PROVIDER: S-EPMC2977658 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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2-(Benzo[d]thia-zol-2-ylsulfan-yl)-N-(6-methyl-2-pyrid-yl)acetamide.

Zhao Bing B Wang Hui H Li Qiang Q Gao Yan Y Liang Dong D

Acta crystallographica. Section E, Structure reports online 20090402 Pt 5

In the title compound, C(15)H(13)N(3)OS(2), the pyridine ring and the benzo[d]thia-zole unit subtend a dihedral angle of 57.7 (2)°. The length of the C(sp) (2)-S bond [1.7462 (17) Å] is significantly shorter than that of the C(sp) (3)-S bond [1.8133 (18) Å]. The crystal structure is stabilized by intra-molecular N-H⋯N and inter-molecular C-H⋯O and C-H⋯N hydrogen-bond inter-actions. Furthermore, C-H⋯π inter-actions stabilize the crystal packing. ...[more]

PMID: 21584001

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