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Ethyl 2-[(4-chloro-phen-yl)hydrazono]-3-oxobutanoate.


ABSTRACT: The mol-ecule of the title oxobutanoate derivative, C(12)H(13)ClN(2)O(3), is nearly planar; the inter-planar angle between the benzene ring and the mean plane through the hydrazono-3-oxobutanoate unit is 2.69?(3)°. An intra-molecular N-H?O hydrogen bond generates an S(6) ring motif. In the crystal packing, C-H?O(3-oxo) inter-actions link mol-ecules into dimers. The dimers thus formed are linked through C-H?O(carboxyl-ate C=O) inter-actions, leading to the formation of ribbons along the [01] direction, which are stabilized via Cl?Cl [3.2916?(3)?Å] contacts. The ribbons are stacked via C?O contacts [3.2367?(12)-3.3948?(12)?Å].

SUBMITTER: Fun HK 

PROVIDER: S-EPMC2977712 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Ethyl 2-[(4-chloro-phen-yl)hydrazono]-3-oxobutanoate.

Fun Hoong-Kun HK   Chantrapromma Suchada S   Padaki Mahesh M   Radhika   Isloor Arun M AM  

Acta crystallographica. Section E, Structure reports online 20090410 Pt 5


The mol-ecule of the title oxobutanoate derivative, C(12)H(13)ClN(2)O(3), is nearly planar; the inter-planar angle between the benzene ring and the mean plane through the hydrazono-3-oxobutanoate unit is 2.69 (3)°. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. In the crystal packing, C-H⋯O(3-oxo) inter-actions link mol-ecules into dimers. The dimers thus formed are linked through C-H⋯O(carboxyl-ate C=O) inter-actions, leading to the formation of ribbons along the [01] dire  ...[more]

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