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Methyl N'-[(E)-2-methoxy-benzyl-idene]-hydrazinecarboxyl-ate.

ABSTRACT: The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol-ecules in the asymmetric unit. The side chains in the two independent mol-ecules have slightly different orientations, with the C=N-N-C torsion angle being 169.19?(14)° in one of the mol-ecules and -179.86?(14)° in the other. Each independent mol-ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol-ecules are linked into chains running along [001] by N-H?O, N-H?N and C-H?O hydrogen bonds. In addition, an inter-molecular C-H?? inter-action is observed.

SUBMITTER: Lv LP 

PROVIDER: S-EPMC2977764 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Methyl N'-[(E)-2-methoxy-benzyl-idene]-hydrazinecarboxyl-ate.

Lv Lu-Ping LP   Yu Wen-Bo WB   Lu Zhong-Hao ZH   Li Wei-Wei WW   Hu Xian-Chao XC  

Acta crystallographica. Section E, Structure reports online 20090422 Pt 5

The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol-ecules in the asymmetric unit. The side chains in the two independent mol-ecules have slightly different orientations, with the C=N-N-C torsion angle being 169.19 (14)° in one of the mol-ecules and -179.86 (14)° in the other. Each independent mol-ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol-ecules are linked into chains running along [001] by N-H⋯O, N-H⋯N and C-H⋯O hydr  ...[more]

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