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2,3,4,6-Tetra-O-acetyl-?-d-galacto-pyranosyl 2-(2,4-dichloro-anilino)-4,4-dimethyl-6-oxocyclo-hex-1-enecarbo-dithio-ate.

ABSTRACT: The cyclo-hexene ring in the title compound, C(29)H(33)Cl(2)NO(10)S(2), adopts an envelope conformation, with the C atom bearing the two methyl groups representing the flap. This atom deviates by 0.63?(1)?Å from the plane through the other five ring atoms (r.m.s. deviation = 0.11?Å). The mol-ecular conformation is stabilized by an intra-molecular N-H?S hydrogen bond. The crystal studied was a non-merohedral twin, with a minor twin component of 29%.

SUBMITTER: El Ashry el SH

PROVIDER: S-EPMC2977784 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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2,3,4,6-Tetra-O-acetyl-β-d-galacto-pyranosyl 2-(2,4-dichloro-anilino)-4,4-dimethyl-6-oxocyclo-hex-1-enecarbo-dithio-ate.

El Ashry El Sayed H el SH Amer Mohammed R MR Shah M Raza MR Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090425 Pt 5

The cyclo-hexene ring in the title compound, C(29)H(33)Cl(2)NO(10)S(2), adopts an envelope conformation, with the C atom bearing the two methyl groups representing the flap. This atom deviates by 0.63 (1) Å from the plane through the other five ring atoms (r.m.s. deviation = 0.11 Å). The mol-ecular conformation is stabilized by an intra-molecular N-H⋯S hydrogen bond. The crystal studied was a non-merohedral twin, with a minor twin component of 29%. ...[more]

PMID: 21583920

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