Unknown

Dataset Information

0

Tetra-?-benzoato-?O:O';?O:O,O';?O,O':O'-bis-[(benzoato-?O,O')(1,10-phenanthroline-?N,N')europium(III)] benzoic acid disolvate.

ABSTRACT: The asymmetric unit of the title complex, [Eu(2)(C(7)H(5)O(2))(6)(C(12)H(8)N(2))(2)]·2C(6)H(5)COOH, contains one-half of the complex mol-ecule, the complete mol-ecule being generated by inversion symmetry, and one benzoic acid solvent mol-ecule. The two Eu(III) ions are linked by four bridging benzoate ions, with an Eu?Eu distance of 3.96041?(12)?Å. Each Eu(III) ion is coordinated by one phenanthroline heterocycle and a bidentate benzoate ion. The irregular nine-coordinated geometry of the metal ion is composed of seven O and two N atoms. The mol-ecular structure is stabilized by intra-molecular C-H?O hydrogen bonds. In the crystal structure, mol-ecules are linked into chains by inter-molecular C-H?O hydrogen bonds along the a axis. The crystal structure is further stabilized by inter-molecular C-H?O and C-H?? inter-actions. Weak ?-? inter-actions are also observed [centroid-centroid distances = 3.6962?(10)-3.6963?(10)?Å].

SUBMITTER: Ooi PH 

PROVIDER: S-EPMC2979066 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tetra-μ-benzoato-κO:O';κO:O,O';κO,O':O'-bis-[(benzoato-κO,O')(1,10-phenanthroline-κN,N')europium(III)] benzoic acid disolvate.

Ooi Ping Howe PH   Teoh Siang Guan SG   Yeap Chin Sing CS   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20100430 Pt 5

The asymmetric unit of the title complex, [Eu(2)(C(7)H(5)O(2))(6)(C(12)H(8)N(2))(2)]·2C(6)H(5)COOH, contains one-half of the complex mol-ecule, the complete mol-ecule being generated by inversion symmetry, and one benzoic acid solvent mol-ecule. The two Eu(III) ions are linked by four bridging benzoate ions, with an Eu⋯Eu distance of 3.96041 (12) Å. Each Eu(III) ion is coordinated by one phenanthroline heterocycle and a bidentate benzoate ion. The irregular nine-coordinated geometry of the metal  ...[more]

Similar Datasets

Unknown Tetra-?-benzoato-?O:O';?O:O,O';?O,O':O'-bis-[(benzoato-?O,O')(1,10-phenanthroline-?N,N')terbium(III)] benzoic acid disolvate.
| S-EPMC2979618 | biostudies-literature
Unknown (Benzoato-?O)bis-(1,10-phenanthroline-?N,N')copper(II) chloride benzoic acid disolvate.
| S-EPMC2979027 | biostudies-literature
Unknown Tetra-kis(μ-2,4-difluoro-benzoato)bis-[(2,4-difluoro-benzoato)(1,10-phenanthroline)gadolinium(III)].
| S-EPMC2960912 | biostudies-literature
Unknown Bis(2,6-dihy-droxy-benzoato-?O,O)(nitrato-?O,O')bis-(1,10-phenanthroline-?N,N')europium(III).
| S-EPMC3011488 | biostudies-literature
Unknown Bis(benzoato-?O,O')(1,10-phenanthroline-?N,N')lead(II) benzoic acid mono-solvate.
| S-EPMC3011696 | biostudies-literature
Unknown Diaqua-bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate.
| S-EPMC2969879 | biostudies-literature
Unknown Diaqua-(2,6-dihy-droxy-benzoato-?O,O)bis-(2,6-dihy-droxy-benzoato-?O)bis-(1,10-phenanthroline-?N,N')lanthanum(III)-1,10-phenanthroline (1/1).
| S-EPMC3011687 | biostudies-literature
Unknown Tetra-kis(?-6-hydr-oxy-1-naphthoato)bis-[(6-hydr-oxy-1-naphthoato)(1,10-phenanthroline)europium(III)] dihydrate.
| S-EPMC2972167 | biostudies-literature
Unknown A dinuclear copper complex: bis-(μ-4-amino-benzoato)bis-[aqua(1,10-phenanthroline)copper(II)] dichloride bis(4-amino-benzoic acid) dihydrate.
| S-EPMC2961994 | biostudies-literature
Unknown Tetra-?-benzoato-?O:O'-bis-[(benzoic acid-?O)nickel(II)].
| S-EPMC2971096 | biostudies-literature