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Redetermination of hexa-sodium hepta-molybdate(VI) 14-hydrate.

ABSTRACT: The structure of the title compound, Na(6)(Mo(7)O(24))·14H(2)O, has been redetermined [Sjöbom & Hedman (1973). Acta Chem. Scand.27, 3673-3674] and the hydrogen atoms have been located. The Na(+) cations adopt distorted octa-hedral geometries and the structure of the [Mo(7)O(24)](6-) anion is consistent with those of other hepta-molbydates. In the crystal, numerous O-H?O hydrogen bonds help to establish the packing.

SUBMITTER: Hao L

PROVIDER: S-EPMC2979069 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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Redetermination of hexa-sodium hepta-molybdate(VI) 14-hydrate.

Hao Lujiang L Chen Jiangkui J Zhang Xiaofei X

Acta crystallographica. Section E, Structure reports online 20100410 Pt 5

The structure of the title compound, Na(6)(Mo(7)O(24))·14H(2)O, has been redetermined [Sjöbom & Hedman (1973). Acta Chem. Scand.27, 3673-3674] and the hydrogen atoms have been located. The Na(+) cations adopt distorted octa-hedral geometries and the structure of the [Mo(7)O(24)](6-) anion is consistent with those of other hepta-molbydates. In the crystal, numerous O-H⋯O hydrogen bonds help to establish the packing. ...[more]

PMID: 21578983

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