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Tetra-kis(?-2-methyl-benzoato-?O:O')bis-[(methanol-?O)copper(II)].

ABSTRACT: In the title compound, [Cu(2)(C(8)H(7)O(2))(4)(CH(3)OH)(2)], the Cu-O bond distances are in the range 1.943?(2)-2.149?(2)?Å within a sligthly distorted square-pyramidal coordination. The Cu?Cu separation is 2.5912?(4)?Å. In the crystal, the mol-ecules are linked into polymeric chains propagating in [001] by inter-molecular O-H?O hydrogen bonds and C-H?? inter-actions.

SUBMITTER: Danish M

PROVIDER: S-EPMC2979172 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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Tetra-kis(μ-2-methyl-benzoato-κO:O')bis-[(methanol-κO)copper(II)].

Danish Muhammad M Saleem Iram I Tahir M Nawaz MN Ahmad Nazir N Raza Abdur Rauf AR

Acta crystallographica. Section E, Structure reports online 20100417 Pt 5

In the title compound, [Cu(2)(C(8)H(7)O(2))(4)(CH(3)OH)(2)], the Cu-O bond distances are in the range 1.943 (2)-2.149 (2) Å within a sligthly distorted square-pyramidal coordination. The Cu⋯Cu separation is 2.5912 (4) Å. In the crystal, the mol-ecules are linked into polymeric chains propagating in [001] by inter-molecular O-H⋯O hydrogen bonds and C-H⋯π inter-actions. ...[more]

PMID: 21579022

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