Di-μ(1,1)-azido-bis-[(2-{1-[2-(isopropyl-amino)ethyl-imino]eth-yl}phenolato)copper(II)].

ABSTRACT: In the centrosymmetric binuclear title complex, [Cu(2)(C(13)H(19)N(2)O)(2)(N(3))(2)], the Cu(II) atom adopts an elongated CuON(4) square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu⋯Cu separation is 3.2365 (3) Å. A pair of intra-molecular N-H⋯O hydrogen bonds helps to establish the mol-ecular conformation.

SUBMITTER: Li HB 

PROVIDER: S-EPMC2979365 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature