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Di-?(1,1)-azido-bis-[(2-{1-[2-(isopropyl-amino)ethyl-imino]eth-yl}phenolato)copper(II)].

ABSTRACT: In the centrosymmetric binuclear title complex, [Cu(2)(C(13)H(19)N(2)O)(2)(N(3))(2)], the Cu(II) atom adopts an elongated CuON(4) square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu?Cu separation is 3.2365?(3)?Å. A pair of intra-molecular N-H?O hydrogen bonds helps to establish the mol-ecular conformation.

SUBMITTER: Li HB

PROVIDER: S-EPMC2979365 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Di-μ(1,1)-azido-bis-[(2-{1-[2-(isopropyl-amino)ethyl-imino]eth-yl}phenolato)copper(II)].

Li He-Bing HB

Acta crystallographica. Section E, Structure reports online 20100515 Pt 6

In the centrosymmetric binuclear title complex, [Cu(2)(C(13)H(19)N(2)O)(2)(N(3))(2)], the Cu(II) atom adopts an elongated CuON(4) square-based pyramidal coordination geometry, arising from the N,N',O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu⋯Cu separation is 3.2365 (3) Å. A pair of intra-molecular N-H⋯O hydrogen bonds helps to establish the mol-ecular conformation. ...[more]

PMID: 21579298

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