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N-Benzyl-2-(2-bromo-phen-yl)-2-(2-nitro-phen-oxy)acetamide.

ABSTRACT: The title compound, C(21)H(17)BrN(2)O(4), a 2-phen-oxy-2-phenyl-acetamide derivative, exhibits a stereogenic center but crystallizes as a racemate as indicated by the centrosymmetric space group. In the mol-ecular structure, the nitro-substituted benzene ring is coplanar [dihedral angle = 12.9?(1)°] with the plane formed by H-N-C(=O)-C=O due to intra-molecular N-H?O hydrogen-bond inter-actions.

SUBMITTER: Li HM

PROVIDER: S-EPMC2979402 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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N-Benzyl-2-(2-bromo-phen-yl)-2-(2-nitro-phen-oxy)acetamide.

Li Huo Ming HM Wu Jin-Long JL

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

The title compound, C(21)H(17)BrN(2)O(4), a 2-phen-oxy-2-phenyl-acetamide derivative, exhibits a stereogenic center but crystallizes as a racemate as indicated by the centrosymmetric space group. In the mol-ecular structure, the nitro-substituted benzene ring is coplanar [dihedral angle = 12.9 (1)°] with the plane formed by H-N-C(=O)-C=O due to intra-molecular N-H⋯O hydrogen-bond inter-actions. ...[more]

PMID: 21579375

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