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Poly[[?(2)-1,2-bis-(diphenyl-phosphan-yl)-1,2-diethylhydrazine]-?(4)-nitrato-?(2)-nitrato-silver(I)].

ABSTRACT: The title compound, [Ag(2)(NO(3))(2)(C(28)H(30)N(2)P(2))](n), crystallizes in polymeric ?-helices. Three O atoms from three different nitrate ions in equatorial positions and two Ag atoms at axial positions set up a trigonal bipyramid. These units are linked by the phosphine ligands into endless helical chains that run along the c axis. The crystal used for the data collection was a racemic twin.

SUBMITTER: Kriel FH

PROVIDER: S-EPMC2979462 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Poly[[μ(2)-1,2-bis-(diphenyl-phosphan-yl)-1,2-diethylhydrazine]-μ(4)-nitrato-μ(2)-nitrato-silver(I)].

Kriel Frederik H FH Fernandes Manuel A MA Coates Judy J

Acta crystallographica. Section E, Structure reports online 20100526 Pt 6

The title compound, [Ag(2)(NO(3))(2)(C(28)H(30)N(2)P(2))](n), crystallizes in polymeric α-helices. Three O atoms from three different nitrate ions in equatorial positions and two Ag atoms at axial positions set up a trigonal bipyramid. These units are linked by the phosphine ligands into endless helical chains that run along the c axis. The crystal used for the data collection was a racemic twin. ...[more]

PMID: 21579343

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catena-Poly[[(nitrato-κO,O')silver(I)]-μ-1,2-bis-(diphenyl-phosphino)ethane-κP:P'].

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