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Diethyl 2-{[3-(2,4,6-trimethyl-benz-yl)-1-phenyl-sulfonyl-1H-indol-2-yl]methyl-idene}propane-dioate.

ABSTRACT: In the title compound, C(32)H(33)NO(6)S, the indole ring system makes dihedral angles of 62.78?(10) and 80.53?(8)°, respectively, with the phenyl and benzene rings. In the crystal, the mol-ecules are linked through inter-molecular C-H?O hydrogen bonds, forming a chain along the a axis. Between the chains, a weak aromatic ?-? stacking inter-action [centroid-centroid distance = 3.831?(2)?Å] is observed.

SUBMITTER: Saravanan B

PROVIDER: S-EPMC2979489 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Diethyl 2-{[3-(2,4,6-trimethyl-benz-yl)-1-phenyl-sulfonyl-1H-indol-2-yl]methyl-idene}propane-dioate.

Saravanan B B Dhayalan V V Mohanakrishnan A K AK Chakkaravarthi G G Manivannan V V

Acta crystallographica. Section E, Structure reports online 20100529 Pt 6

In the title compound, C(32)H(33)NO(6)S, the indole ring system makes dihedral angles of 62.78 (10) and 80.53 (8)°, respectively, with the phenyl and benzene rings. In the crystal, the mol-ecules are linked through inter-molecular C-H⋯O hydrogen bonds, forming a chain along the a axis. Between the chains, a weak aromatic π-π stacking inter-action [centroid-centroid distance = 3.831 (2) Å] is observed. ...[more]

PMID: 21579568

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