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4-Methyl-N-(2-methyl-benzo-yl)benzene-sulfonamide.

ABSTRACT: In the title compound, C(15)H(15)NO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. Further, the conformation of the C=O bond is syn to the ortho-methyl group in the benzoyl ring. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 87.1?(1)° and that between the sulfonyl and the benzoyl benzene rings is 58.2?(1)°. In the crystal structure, mol-ecules are linked by pairs of N-H?O(S) hydrogen bonds, forming inversion dimers.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2979502 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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4-Methyl-N-(2-methyl-benzo-yl)benzene-sulfonamide.

Gowda B Thimme BT Foro Sabine S Suchetan P A PA Fuess Hartmut H

Acta crystallographica. Section E, Structure reports online 20100529 Pt 6

In the title compound, C(15)H(15)NO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. Further, the conformation of the C=O bond is syn to the ortho-methyl group in the benzoyl ring. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 87.1 (1)° and that between the sulfonyl and the benzoyl benzene rings is 58.2 (1)°. In the crystal structure, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming inversion d ...[more]

PMID: 21579562

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