Ontology highlight
ABSTRACT:
SUBMITTER: Schulz S
PROVIDER: S-EPMC2979608 | biostudies-literature | 2010 May
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100529 Pt 6
The title compound, [Rh(C(8)H(12))(C(14)H(28)P(2))]BF(4), exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate η(2),η(2)-coordinated cyclo-octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol-ecules in the asymmetric unit and intra-molecular P-Rh-P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P-Rh-P and the X-Rh-X plan ...[more]