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Bis(?-4-fluoro-2,6-diformyl-phenolato)bis-[diaqua-nickel(II)] dichloride.

ABSTRACT: In the title dinuclear nickel(II) complex, [Ni(2)(C(8)H(4)FO(3))(2)(H(2)O)(4)]Cl(2), synthesized by the reaction between 4-fluoro-2,6-diformyl-phenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the Ni(II) atom adopts a slightly distorted octa-hedral coordination geometry. The two Ni atoms are bridged by two phenolate O atoms and the intra-molecular Ni?Ni distance is 3.0751?(9)?Å. The crystal structure is stabilized by O-H?Cl hydrogen bonds.

SUBMITTER: Zheng Y

PROVIDER: S-EPMC2979620 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Bis(μ-4-fluoro-2,6-diformyl-phenolato)bis-[diaqua-nickel(II)] dichloride.

Zheng Yin Y Li Shi-Rong SR Zhou Hong H Pan Zhi-Quan ZQ Li Yi-Zhi YZ

Acta crystallographica. Section E, Structure reports online 20100519 Pt 6

In the title dinuclear nickel(II) complex, [Ni(2)(C(8)H(4)FO(3))(2)(H(2)O)(4)]Cl(2), synthesized by the reaction between 4-fluoro-2,6-diformyl-phenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the Ni(II) atom adopts a slightly distorted octa-hedral coordination geometry. The two Ni atoms are bridged by two phenolate O atoms and the intra-molecular Ni⋯Ni distance is 3.0751 (9) Å. The crystal structure is stabilized by O-H⋯Cl hydrogen bonds. ...[more]

PMID: 21579311

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