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[(Z)-O-Ethyl N-(4-chloro-phen-yl)thio-carbamato-?S](triphenyl-phosphine-?P)gold(I) dichloro-methane hemisolvate.

ABSTRACT: The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01?(4)°]; a close intra-molecular Au?O contact [2.964?(4)?Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H?N, C-H?S and C-H?? inter-actions. The solvent mol-ecule is disordered about a twofold rotation axis.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2979641 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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[(Z)-O-Ethyl N-(4-chloro-phen-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I) dichloro-methane hemisolvate.

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100522 Pt 6

The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01 (4)°]; a close intra-molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H⋯N, C-H⋯S and C-H⋯π inter-actions. The solvent mol-ecule is disordered about a twofold rotation axis. ...[more]

PMID: 21579326

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