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ABSTRACT:
SUBMITTER: Tadbuppa PP
PROVIDER: S-EPMC2979641 | biostudies-literature | 2010 May
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100522 Pt 6
The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01 (4)°]; a close intra-molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H⋯N, C-H⋯S and C-H⋯π inter-actions. The solvent mol-ecule is disordered about a twofold rotation axis. ...[more]