Unknown

Dataset Information

0

2,9-Bis(trichloro-meth-yl)-1,10-phenanthroline.

ABSTRACT: The asymmetric unit of the title compound, C(14)H(6)Cl(6)N(2), contains two crystallographically independent mol-ecules, each of which is slightly twisted from planarity. The dihedral angles between the central ring and the two outer rings are 3.81?(7) and 4.30?(7)° in one mol-ecule, and 4.13?(8) and 4.10?(7)° in the other. In the crystal structure, mol-ecules are inter-linked by C-Cl?Cl inter-actions into sheets parallel to the ac plane. These sheets are stacked along the b axis in such a way that the mol-ecules are anti-parallel; they are further connected into a supra-molecular network. There are no classical hydrogen bonds. C?Cl [3.637?(2)?Å], Cl?Cl [3.5639?(5)-3.6807?(8)?Å] and Cl?N [3.3802?(15)-3.4093?(15)?Å] short contacts and ?-? inter-actions, with centroid-centroid distances in the range 3.5868?(9)-3.7844?(9)?Å, are observed.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC2979670 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

2,9-Bis(trichloro-meth-yl)-1,10-phenanthroline.

Fun Hoong-Kun HK   Chantrapromma Suchada S   Maity Annada C AC   Goswami Shyamaprosad S  

Acta crystallographica. Section E, Structure reports online 20100123 Pt 2

The asymmetric unit of the title compound, C(14)H(6)Cl(6)N(2), contains two crystallographically independent mol-ecules, each of which is slightly twisted from planarity. The dihedral angles between the central ring and the two outer rings are 3.81 (7) and 4.30 (7)° in one mol-ecule, and 4.13 (8) and 4.10 (7)° in the other. In the crystal structure, mol-ecules are inter-linked by C-Cl⋯Cl inter-actions into sheets parallel to the ac plane. These sheets are stacked along the b axis in such a way t  ...[more]

Similar Datasets

Unknown 4,7-Diphenyl-2,9-bis-(trichloro-meth-yl)-1,10-phenanthroline.
| S-EPMC2980224 | biostudies-literature
Unknown 2,9-Bis(4-pyridylmeth-oxy)-1,10-phenanthroline.
| S-EPMC2970499 | biostudies-literature
Unknown 2,9-Bis(1,3-benzothia-zol-2-yl)-1,10-phenanthroline dichloro-methane disolvate.
| S-EPMC2960670 | biostudies-literature
Unknown Tris(1,10-phenanthroline)cobalt(II) bis-(trichloro-acetate).
| S-EPMC3152094 | biostudies-literature
Unknown Aqua-(2,9-dimethyl-1,10-phenanthroline-?N,N')bis-(2-hydroxy-benzoato-?O)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate.
| S-EPMC2968132 | biostudies-literature
Unknown 2,9-Dichloro-1,10-phenanthroline.
| S-EPMC2969030 | biostudies-literature
Unknown Aqua-(2,9-dimethyl-1,10-phenanthroline-?N,N')bis-(3-hydroxy-benzoato-?O)manganese(II)-2,9-dimethyl-1,10-phenanthroline-water (1/1/1).
| S-EPMC2977455 | biostudies-literature
Unknown Bis(2,9-dimethyl-1,10-phenanthroline-κN,N')bis-(nitrato-κO,O')lead(II).
| S-EPMC3006962 | biostudies-literature
Unknown [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-?N)-1,10-phenanthroline-?N,N']bis-(thio-cyanato-?N)cadmium(II).
| S-EPMC3050342 | biostudies-literature
Unknown 2,9-Bis(5-sulfanylidene-4,5-di-hydro-1,3,4-oxa-diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate.
| S-EPMC3998466 | biostudies-literature