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Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl-idene)(p-tol-yl)meth-yl]amino}-3-phenyl-propanoate.

ABSTRACT: The asymmetric unit of the title compound, C(29)H(29)N(3)O(3), contains two mol-ecules, which exist in their enamine-keto form, being stabilized by strong intra-molecular N-H?O hydrogen bonds, which generate S(6) loops. In the crystal, inter-molecular C-H?O hydrogen bonds link the mol-ecules into chains, which are further linked by weak C-H?? inter-actions, forming a two-dimensional network.

SUBMITTER: Zhang X

PROVIDER: S-EPMC2979726 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl-idene)(p-tol-yl)meth-yl]amino}-3-phenyl-propanoate.

Zhang Xin X Huang Meng M Du Cong C Han Junjing J

Acta crystallographica. Section E, Structure reports online 20100109 Pt 2

The asymmetric unit of the title compound, C(29)H(29)N(3)O(3), contains two mol-ecules, which exist in their enamine-keto form, being stabilized by strong intra-molecular N-H⋯O hydrogen bonds, which generate S(6) loops. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into chains, which are further linked by weak C-H⋯π inter-actions, forming a two-dimensional network. ...[more]

PMID: 21579710

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