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Tert-Butyl 2-benzoyl-2-methyl-propanoate.

ABSTRACT: The title compound, C(15)H(20)O(3), is bent with a dihedral angle of 67.28?(9)° between the mean planes of the phenyl ring and a group encompassing the ester functionality (O=C-O-C). In the crystal, mol-ecules related by inversion symmetry are connected by weak C-H?O inter-actions into infinite chains. On one side of the mol-ecule there are two adjacent inter-actions between neighbouring mol-ecules involving the H atoms of methyl groups from the dimethyl groups and the O atoms of the ketone; on the other side, there are also two inter-actions to another adjacent mol-ecule involving the H atoms on the phenyl rings and the carbonyl O atoms of the ester functionality.

SUBMITTER: Logue MW

PROVIDER: S-EPMC2979963 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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tert-Butyl 2-benzoyl-2-methyl-propanoate.

Logue Marshall W MW Luck Rudy L RL Maynard Nicklaus S NS Orlowski Sandra S SS Pignotti Louis R LR Putman Annie L AL Whelan Kelli M KM

Acta crystallographica. Section E, Structure reports online 20100130 Pt 2

The title compound, C(15)H(20)O(3), is bent with a dihedral angle of 67.28 (9)° between the mean planes of the phenyl ring and a group encompassing the ester functionality (O=C-O-C). In the crystal, mol-ecules related by inversion symmetry are connected by weak C-H⋯O inter-actions into infinite chains. On one side of the mol-ecule there are two adjacent inter-actions between neighbouring mol-ecules involving the H atoms of methyl groups from the dimethyl groups and the O atoms of the ketone; on ...[more]

PMID: 21579896

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2013-09-01 | GSE46371 | GEO

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