Browse
Submit Data
Databases
API
Help

Dataset Information

26 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{2-[2-(Ethyl-amino)ethyl-imino-meth-yl]-5-methoxy-phenolato}thio-cyanato-nickel(II).

ABSTRACT: In the title mononuclear nickel(II) complex, [Ni(C(12)H(17)N(2)O(2))(NCS)], the metal atom is four-coordinated in a tetra-hedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thio-cyanate ligand. In the crystal structure, centrosymmetrically related mol-ecules are linked into dimers through inter-molecular N-H⋯O hydrogen bonds. These dimers are further connected by inter-molecular C-H⋯S hydrogen bonds, forming chains running parallel to [101].

SUBMITTER: Liu L

PROVIDER: S-EPMC2979965 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

{2-[2-(Ethyl-amino)ethyl-imino-meth-yl]-5-methoxy-phenolato}(thio-cyanato-?N)-copper(II).

Project description:In the title mononuclear copper(II) complex, [Cu(C(12)H(17)N(2)O(2))(NCS)], the Cu(II) atom is four-coordinated by an NNO-donor set of the tridentate Schiff base ligand and the N atom of a terminal thio-cyanate ligand in a slightly distorted square-planar geometry.

| S-EPMC2984064 | biostudies-literature

{4-Bromo-2-[2-(isopropyl-amino)ethyl-imino-meth-yl]phenolato}thio-cyanato-copper(II).

Project description:In the title mononuclear Schiff base copper(II) complex, [Cu(C(12)H(16)BrN(2)O)(NCS)], the Cu(II) ion is coordinated by two N atoms and one O atom from a Schiff base ligand, and by one N atom from a thio-cyanate anion, giving a square-planar geometry. There are long-range inter-actions between the Cu atom and S [3.151?(5)?Å] and Br [3.929?(5)?Å] atoms above and below the square plane.

| S-EPMC2961070 | biostudies-literature

{2-[2-(Isopropyl-amino)-ethyl-imino-meth-yl]-5-meth-oxy-phenolato}(thio-cyanato--?N)nickel(II).

Project description:In the title mononuclear complex, [Ni(C(13)H(19)N(2)O(2))(NCS)], the Ni(II) ion is coordinated by one phenolate O atom, one imine N atom, and one amine N atom of a 2-[2-(isopropyl-amino)-ethyl-imino-meth-yl]-5-meth-oxy-phenolate Schiff base ligand, and by one N atom of a thio-cyanate ligand, forming a slightly distorted square-planar geometry.

| S-EPMC3007448 | biostudies-other

Di-?-thio-cyanato-bis-({2,4-dichloro-6-[2-(diethyl-amino)ethyl-imino-meth-yl]phenolato}copper(II)).

Project description:The title compound, [Cu(2)(NCS)(2)(C(13)H(17)Cl(2)N(2)O)(2)], was obtained by the reaction of 3,5-dichloro-salicylaldehyde, N,N-diethyl-ethane-1,2-diamine, sodium thio-cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu?S axial bond [2.972?(3)?Å]. The Cu atom is five-coordinated by the three donor atoms of the Schiff base ligand, 2,4-dichloro-6-[(2-diethyl-amino-ethyl-imino)meth-yl]phenol, one N atom of a thio-cyanate group, and one S atom of a symmetry-related thio-cyanate group, forming a slightly distorted square-pyramidal geometry.

| S-EPMC2915145 | biostudies-literature

cis-Bis[2-(cyclo-propyl-imino-meth-yl)-6-methoxy-phenolato]bis-(thio-cyanato)cobalt(II).

Project description:In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio-cyanate ligands, forming a distorted octa-hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N-H⋯O hydrogen bond is present.

| S-EPMC2914956 | biostudies-literature

(2-{[2-(2-Amino-ethyl-amino)-eth-yl]imino-meth-yl}phenolato)nickel(II) chloride dihydrate.

Project description:In the title complex, [Ni(C(11)H(16)N(3)O)]Cl·2H(2)O, the Ni(II) ion is coordinated within a distorted square-planar environment. In the crystal, inter-molecular N-H?Cl, N-H?O, O-H?O, O-H?Cl and weak C-H?O hydrogen bonds link the components into a two-dimensional network parallel to (001).

| S-EPMC3050410 | biostudies-literature

Bis{2-eth-oxy-6-[2-(ethyl-ammonio)ethyl-imino-meth-yl]phenolato}thio-cyanato-zinc(II) nitrate.

Project description:The title complex, [Zn(NCS)(C(13)H(20)N(2)O(2))(2)]NO(3), consists of a complex mononuclear Zn(II) cation and a nitrate counter-anion. The Zn(II) ion is five-coordinate in a trigonal-bipyramidal geometry. The thio-cyanate N atom and two O atoms from two Schiff bases define the equatorial plane, and the two imine N atoms from the same two Schiff bases occupy the axial positions, with an N-Zn-N angle of 175.98?(7)°. The amine N atoms of the Schiff base ligands are protonated and are not involved in the coordination to the metal. The dihedral angle between the two substituted benzene rings is 87.7?(2)°. The nitrate counter-ions are linked to the cations through N-H?O hydrogen bonds.

| S-EPMC2959439 | biostudies-literature

{2-Bromo-4-chloro-6-[2-(diethyl-amino)ethyl-imino-meth-yl]phenolato-?N,N',O}(thio-cyanato-?N)copper(II).

Project description:In the title compound, [Cu(C(13)H(17)BrClN(2)O)(NCS)], the Cu atom is in a slightly distorted square-planar geometry, coordinated by the three donor atoms of the ligand and the N atom of the isothio-cyanate group.

| S-EPMC2915066 | biostudies-literature

Bis{2-[2-(isopropyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato}nickel(II) dithio-cyanate.

Project description:The title complex, [Ni(C(13)H(20)N(2)O(2))(2)](NCS)(2), consists of a centrosymmetric mononuclear four-coordinate nickel(II) complex cation and two thio-cyanate anions. The Ni atom is located on an inversion center and is coordinated by two phenol O atoms and two imine N atoms from two equivalent Schiff base ligands, in a square-planar geometry. In the crystal structure, the amino H atoms are involved in N-H⋯O hydrogen bonds with the phenol and meth-oxy O atoms of the ligand, and in N-H⋯N hydrogen bonds with the N atoms of the thio-cyanate anions, which sit above and below the Ni atom.

| S-EPMC2960988 | biostudies-literature

Bis{2-eth-oxy-6-[2-(isopropyl-ammonio)ethyl-imino-meth-yl]phenolato}dithio-cyanato-nickel(II).

Project description:In the mononuclear title complex, [Ni(NCS)(2)(C(14)H(22)N(2)O(2))(2)], the Ni atom lies on an inversion centre. It is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands, and is also coordinated by the N atoms from two thio-cyanate ligands, giving a slightly distorted octa-hedral geometry. Intra-molecular N-H?O and N-H?N hydrogen bonds are observed.

| S-EPMC2979711 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data