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N-(2,5-Dimethyl-phen-yl)-4-methyl-benzene-sulfonamide.

ABSTRACT: In the crystal structure of the title compound, C(15)H(17)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -61.0 (2)°. The dihedral angle between the two aromatic rings is 49.4 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2979993 | biostudies-literature |

REPOSITORIES: biostudies-literature

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4-Chloro-N-(2,5-dimethyl-phen-yl)-2-methyl-benzene-sulfonamide.

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Project description:In the title compound, C(14)H(13)Cl(2)NO(2)S, the dihedral angle between the aromatic rings is 62.21 (7)° and the C-S-N-C group adopts a gauche conformation [torsion angle = 60.22 (17)°]. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into C(4) chains propagating in [010]. A short inter-molecular Cl⋯O contact of 3.1115 (17) Å is seen.

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Project description:In the title compound, C(15)H(17)NO(2)S, the dihedral angle between the two aromatic rings is 53.9?(1)°. The crystal structure features inversion-related dimers linked by N-H?O hydrogen bonds.

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Project description:In the title compound, C(15)H(17)NO(2)S, the mol-ecule is bent at the S atom, the C-SO(2)-NH-C torsion angle being 88.0?(2)°. The dihedral angle between the two aromatic rings is 49.8?(1)°. In the crystal, mol-ecules are linked into zigzag chains parallel to the a axis via N-H?O hydrogen bonds.

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2,4-Dimethyl-N-(4-methyl-phen-yl)benzene-sulfonamide.

Project description:The asymmetric unit of the crystal of the title compound, C(15)H(17)NO(2)S, contains two independent mol-ecules, which are twisted at the S-N bonds with C-SO(2)-NH-C torsion angles of 48.3?(2) (mol-ecule 1) and -75.7?(3)° (mol-ecule 2). The dihedral angles between the benzene rings are 72.0?(1) (mol-ecule 1) and 78.3?(1)° (mol-ecule 2). The crystal structure features inversion dimers linked by pairs of N-H?O hydrogen bonds.

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