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Bis[2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolato-?N,O]copper(II).

ABSTRACT: In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61?(6)° between the planes of the two six-membered rings. The pyridyl ring was refined using a disorder model with approximately 70% occupancy for the major component.

SUBMITTER: Chen X

PROVIDER: S-EPMC2980013 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Bis[2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolato-κN,O]copper(II).

Chen Xiaodan X Sun Yu Y Yao Qingzhao Q Zhang Huaihong H Liang Qing Q

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title complex, [Cu(C(14)H(13)N(2)O(2))(2)], the Cu(II) ion is located on a crystallographic inversion center. The complex thus adopts a square-planar trans-[CuN(2)O(2)] coordination geometry, with the Cu(II) ion coordinated by two 2-meth-oxy-6-(3-pyridylmethyl-imino-meth-yl)phenolate (Schiff base) ligands. The aryl and pyridyl rings in the Schiff base are almost perpendicular to each other, with a dihedral angle of 87.61 (6)° between the planes of the two six-membered rings. The pyridyl r ...[more]

PMID: 21579937

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