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2-(2H-Tetra-zol-5-yl)pyridinium perchlorate monohydrate.

ABSTRACT: In the cation of the title compound, C(6)H(6)N(5) (+)·ClO(4) (-)·H(2)O, the pyridinium and tetra-zole rings are essentially coplanar, making a dihedral angle of 1.2?(2)°. In the crystal, inter-molecular N-H?O and O-H?O hydrogen bonds link the cations, anions and water mol-ecules into a ribbon-like structure along the c axis. Adjacent ribbons are linked via ?-? stacking inter-actions between the tetra-zole rings, with a centroid-centroid distance of 3.484?(2)?Å.

SUBMITTER: Dai J

PROVIDER: S-EPMC2980014 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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2-(2H-Tetra-zol-5-yl)pyridinium perchlorate monohydrate.

Dai Jing J Zheng Wen-Ni WN

Acta crystallographica. Section E, Structure reports online 20091209 Pt 1

In the cation of the title compound, C(6)H(6)N(5) (+)·ClO(4) (-)·H(2)O, the pyridinium and tetra-zole rings are essentially coplanar, making a dihedral angle of 1.2 (2)°. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the cations, anions and water mol-ecules into a ribbon-like structure along the c axis. Adjacent ribbons are linked via π-π stacking inter-actions between the tetra-zole rings, with a centroid-centroid distance of 3.484 (2) Å. ...[more]

PMID: 21580172

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4-(2H-Tetra-zol-5-yl)pyridinium perchlorate.

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