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Scheelite-type NaDy(WO(4))(2).

ABSTRACT: The title compound sodium dysprosium(III) bis-[tungs-tate(VI)], NaDy(WO(4))(2), has been synthesized under high temperature solution growth (HTSG) conditions in air. The compound crystallizes with the scheelite structure and is composed of isolated WO(4) tetra-hedra ( symmetry) with one set of bond lengths and distorted [(Na/Dy)O(8)] dodeca-hedra ( symmetry; occupancy ratio Na:Dy = 1:1) with two sets of bond lengths.

SUBMITTER: Zhao D

PROVIDER: S-EPMC2980022 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Scheelite-type NaDy(WO(4))(2).

Zhao Dan D Li Feifei F Cheng Wendan W Zhang Hao H

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

The title compound sodium dysprosium(III) bis-[tungs-tate(VI)], NaDy(WO(4))(2), has been synthesized under high temperature solution growth (HTSG) conditions in air. The compound crystallizes with the scheelite structure and is composed of isolated WO(4) tetra-hedra ( symmetry) with one set of bond lengths and distorted [(Na/Dy)O(8)] dodeca-hedra ( symmetry; occupancy ratio Na:Dy = 1:1) with two sets of bond lengths. ...[more]

PMID: 21579906

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Project description:A set of new triple molybdates, LixNa1-xCaGd0.5(MoO4)3:Ho3+0.05/Yb3+0.45, was successfully manufactured by the microwave-accompanied sol-gel-based process (MAS). Yellow molybdate phosphors LixNa1-xCaGd0.5(MoO4)3:Ho3+0.05/Yb3+0.45 with variation of the LixNa1-x (x = 0, 0.05, 0.1, 0.2, 0.3) ratio under constant doping amounts of Ho3+ = 0.05 and Yb3+ = 0.45 were obtained, and the effect of Li+ on their spectroscopic features was investigated. The crystal structures of LixNa1-xCaGd0.5(MoO4)3:Ho3+0.05/Yb3+0.45 (x = 0, 0.05, 0.1, 0.2, 0.3) at room temperature were determined in space group I41/a by Rietveld analysis. Pure NaCaGd0.5Ho0.05Yb0.45(MoO4)3 has a scheelite-type structure with cell parameters a = 5.2077 (2) and c = 11.3657 (5) Å, V = 308.24 (3) Å3, Z = 4. In Li-doped samples, big cation sites are occupied by a mixture of (Li,Na,Gd,Ho,Yb) ions, and this provides a linear cell volume decrease with increasing Li doping level. The evaluated upconversion (UC) behavior and Raman spectroscopic results of the phosphors are discussed in detail. Under excitation at 980 nm, the phosphors provide yellow color emission based on the 5S2/5F4 → 5I8 green emission and the 5F5 → 5I8 red emission. The incorporated Li+ ions gave rise to local symmetry distortion (LSD) around the cations in the substituted crystalline structure by the Ho3+ and Yb3+ ions, and they further affected the UC transition probabilities in triple molybdates LixNa1-xCaGd0.5(MoO4)3:Ho3+0.05/Yb3+0.45. The complex UC intensity dependence on the Li content is explained by the specificity of unit cell distortion in a disordered large ion system within the scheelite crystal structure. The Raman spectra of LixNa1-xCaGd0.5(MoO4)3 doped with Ho3+ and Yb3+ ions were totally superimposed with the luminescence signal of Ho3+ ions in the range of Mo-O stretching vibrations, and increasing the Li+ content resulted in a change in the Ho3+ multiplet intensity. The individual chromaticity points (ICP) for the LiNaCaGd(MoO4)3:Ho3+,Yb3+ phosphors correspond to the equal-energy point in the standard CIE (Commission Internationale de L'Eclairage) coordinates.

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Scheelite-type NaDy(WO(4))(2).

Publications

Scheelite-type NaDy(WO(4))(2).

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