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Bis(propan-2-yl) [(1S)-1-(4-fluoro-phen-yl)-1-hydr-oxy-2-nitro-ethyl]phospho-nate.

ABSTRACT: In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P-C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra-molecular chains mediated by O-H?O hydrogen bonds, which propagate in the a-axis direction. A C-H?O inter-action consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60?(2):0.40?(2) occupancy ratio for the two components.

SUBMITTER: Mandal T

PROVIDER: S-EPMC2980027 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Bis(propan-2-yl) [(1S)-1-(4-fluoro-phen-yl)-1-hydr-oxy-2-nitro-ethyl]phospho-nate.

Mandal Tanmay T Samanta Sampak S Broker Grant A GA Zhao Cong-Gui CG Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P-C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supra-molecular chains mediated by O-H⋯O hydrogen bonds, which propagate in the a-axis direction. A C-H⋯O inter-action consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components. ...[more]

PMID: 21580194

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