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Catena-Poly[[diaqua-dichlorido-manganese(II)]-?-1,1'-bis-(1H-1,2,4-triazol-1-ylmeth-yl)ferrocene].

ABSTRACT: In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octa-hedrally coordinated by two N atoms from two adjacent 1,1'-bis-(1H-1,2,4-triazol-1-ylmeth-yl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water mol-ecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by inter-molecular O-H?N hydrogen bonds, which link the chains, forming a two-dimensional layer parallel to (10); O-H?Cl inter-actions link the layers, forming a three-dimensional network.

SUBMITTER: Shi CY

PROVIDER: S-EPMC2980034 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[diaqua-dichlorido-manganese(II)]-μ-1,1'-bis-(1H-1,2,4-triazol-1-ylmeth-yl)ferrocene].

Shi Chong-Yu CY Zhou Xiao-Li XL Wu Bo B Zhu Ni N Weia Zhen-Shu ZS

Acta crystallographica. Section E, Structure reports online 20091224 Pt 1

In the title complex, [FeMn(C(8)H(8)N(3))(2)Cl(2)(H(2)O)(2)](n), the Mn(II) atom, located on an inversion center, is octa-hedrally coordinated by two N atoms from two adjacent 1,1'-bis-(1H-1,2,4-triazol-1-ylmeth-yl)ferrocene (btmf) ligands and two Cl atoms forming the equatorial plane, with the axial positions occupied by two O atoms of coordinated water mol-ecules. The btmf ligands link adjoining Mn(II) atoms into a zigzag chain along the a axis. The crystal structure is stabilized by inter-mol ...[more]

PMID: 21579985

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