Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N-(2,4-Dichloro-phen-yl)benzene-sulfonamide.

ABSTRACT: The title compound, C(12)H(9)Cl(2)NO(2)S, crystallizes with two independent mol-ecules in the asymmetric unit. The dihedral angles between the two aromatic rings are 70.8?(1) and 74.8?(1)° for the two mol-ecules. The crystal structure features dimers made up of one each of the two asymmetric molecules linked by pairs of N-H?O hydrogen bonds. An intra-molecular N-H?Cl hydrogen bond is also observed in both mol-ecules.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2980121 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

N-(2,4-Dichloro-phen-yl)benzene-sulfonamide.

Gowda B Thimme BT Foro Sabine S Nirmala P G PG Fuess Hartmut H

Acta crystallographica. Section E, Structure reports online 20091224 Pt 1

The title compound, C(12)H(9)Cl(2)NO(2)S, crystallizes with two independent mol-ecules in the asymmetric unit. The dihedral angles between the two aromatic rings are 70.8 (1) and 74.8 (1)° for the two mol-ecules. The crystal structure features dimers made up of one each of the two asymmetric molecules linked by pairs of N-H⋯O hydrogen bonds. An intra-molecular N-H⋯Cl hydrogen bond is also observed in both mol-ecules. ...[more]

PMID: 21580110

Similar Datasets

2,4-Dichloro-N-(3,4-dichloro-phen-yl)benzene-sulfonamide.

Project description:In the crystal structure of the title compound, C(12)H(7)Cl(4)NO(2)S, the conformation of the N-H bond is syn to the meta-chloro residue in the aniline benzene ring. The two aromatic rings are tilted relative to each other by 68.9?(1)°. N-H?O hydrogen bonds connect the mol-ecules into centrosymmetric dimers.

| S-EPMC2977279 | biostudies-literature

2,4-Dichloro-N-(2,3-dichloro-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(12)H(7)Cl(4)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the ortho-Cl atoms in the aniline and sulfonyl benzene rings. The C-SO(2)-NH-C torsion angle is -51.98?(18)°. The sulfonyl and aniline benzene rings are tilted by 67.7?(1)° relative to each other. An intra-molecular N-H?Cl hydrogen bond occurs.

| S-EPMC3247310 | biostudies-literature

2,4-Dichloro-N-(3,5-dichloro-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(12)H(7)Cl(4)NO(2)S, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the ortho-Cl atom of the sulfonyl-benzene ring and one of the meta-Cl atoms of the aniline ring. The C-SO(2)-NH-C torsion angle is -93.9?(2)°. The benzene rings are tilted relative to each other by 61.9?(1)°. The crystal structure features inversion-related dimers linked by pairs of N-H?O hydrogen bonds.

| S-EPMC3247380 | biostudies-literature

N-(2,4-Dichloro-phen-yl)-2,4-dimethyl-benzene-sulfonamide.

Project description:In the title compound, C(14)H(13)Cl(2)NO(2)S, the mol-ecule is bent at the S atom with an C-SO(2)-NH-C torsion angle of -69.9?(2)°. The dihedral angle between the sulfonyl and aniline benzene rings is 44.0?(1)°. The crystal structure features inversion dimers linked by pairs of N-H?O hydrogen bonds. An intra-molecular N-H?Cl hydrogen bond is also observed.

| S-EPMC3011417 | biostudies-literature

2,4-Dichloro-N-(2,4-dimethyl-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(14)H(13)Cl(2)NO(2)S, the C-SO(2)-NH-C torsion angle is -71.4?(4)°. The sulfonyl and aniline benzene rings are tilted relative to one another by 44.6?(1)°. The crystal structure features inversion-related dimers linked by pairs of N-H?O hydrogen bonds.

| S-EPMC3247564 | biostudies-literature

N-(2,3-Dichloro-phen-yl)-2,4-dimethyl-benzene-sulfonamide.

Project description:In the title compound, C(14)H(13)Cl(2)NO(2)S, the dihedral angle between the two aromatic rings is 70.4?(1)°. The mol-ecular conformation is stabilized by an intra-molecular N-H?Cl hydrogen bond.

| S-EPMC3011480 | biostudies-literature

N-(3,5-Dichloro-phen-yl)-2,4-dimethyl-benzene-sulfonamide.

Project description:In the crystal structure of the title compound, C(14)H(13)Cl(2)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the N atom, with an C-SO(2)-NH-C torsion angle of -54.9?(3)°. The two benzene rings are tilted relative to each other by 82.3?(2)°. The mol-ecules are linked into centrosymmetric R(2) (2)(8) motifs by N-H?O hydrogen bonds and C-H?? inter-actions along [100].

| S-EPMC2979206 | biostudies-literature

2,4-Dichloro-N-(2,5-dimethyl-phen-yl)benzene-sulfonamide.

Project description:The asymmetric unit of the title compound, C(14)H(13)Cl(2)NO(2)S, contains three independent moleules. The torsion angles of the C-SO2-NH-C segments in the three mol-ecules are 67.5?(2), 83.4?(2) and -77.5?(2)°. The two aromatic rings are tilted relative to each other by 68.8?(1), 64.1?(1) and 68.5?(1)°. The crystal structure features dimers linked by pairs of N-H?O hydrogen bonds.

| S-EPMC3201254 | biostudies-literature

2,4-Dichloro-N-(3,4-dimethyl-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(14)H(13)Cl(2)NO(2)S, the C-SO(2)-NH-C torsion angle is -60.84?(18). The sulfonyl and the aniline benzene rings are tilted relative to each other by 66.4?(1)°. The crystal structure features inversion-related dimers linked by pairs of N-H?O hydrogen bonds.

| S-EPMC3201316 | biostudies-literature

2,4-Dichloro-N-(2,6-dimethyl-phen-yl)benzene-sulfonamide.

Project description:In the crystal of the title compound, C(14)H(13)Cl(2)NO(2)S, the N-H bond in the C-SO(2)-NH-C segment orients itself away from the two ortho-methyl groups in the aniline benzene ring and towards the ortho-chloro group of the sulfonyl benzene ring. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -100.48?(18)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 69.6?(1)°. Inter-molecular N-H?O hydrogen bonds link the mol-ecules into infinite chains.

| S-EPMC3201408 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data