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Catena-Poly[[trimethyl-tin(IV)]-?-(1,1'-binaphthyl-2,2'-diyl phospho-nato)].

ABSTRACT: In the title polymeric coordination compound, [Sn(CH(3))(3)(C(20)H(12)O(4)P)](n), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the phosphate O atoms of the 1,1'-binaphthyl-2,2'-diyl phospho-nate ligands in axial positions and equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 1,1'-binaphthyl-2,2'-diyl phospho-nate ligand, forming a one-dimensional chain structure parallel to the b axis.

SUBMITTER: Wu J

PROVIDER: S-EPMC2980144 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[trimethyl-tin(IV)]-μ-(1,1'-binaphthyl-2,2'-diyl phospho-nato)].

Wu Jianjun J Zhang Rufen R

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title polymeric coordination compound, [Sn(CH(3))(3)(C(20)H(12)O(4)P)](n), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the phosphate O atoms of the 1,1'-binaphthyl-2,2'-diyl phospho-nate ligands in axial positions and equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 1,1'-binaphthyl-2,2'-diyl phospho-nate ligand, forming a one-dimensional chain structure parallel to the b axis ...[more]

PMID: 21579958

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